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Polyols are active hydrogen monomers based on polyesters, polyethers, or hydrocarbon materials that contain at least two active hydrogen atoms. The type of polyol used will determine whether the foam produced is flexible or rigid. Since most polyols immediately react with isocyanates when added together, it is easy to combine the polymerization and shaping processes into one step. During the polymerization proccess, the polyol and polyisocyanate molecules link and interconnect together to form a three dimensional material.

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Most foams consist of the following chemicals: 50% polyol, 40% polyisocyanates, and 10% water and other chemicals. Polyisocyanates and polyols are liquid polymers that, when combined with water, produce an exothermic (heat generating) reaction forming the polyurethane. The two polyisocyanates most commonly used are diphenylethane diisocyanate (MDI) and toluene diisocyanate (TDI). Both are derived from readily available petrochemicals and are manufactured by well-established chemical processes. Though MDI is chemically more complex than TDI, this complexity allows its composition to be tailored for each specific application. MDI is generally used in rigid foams, whereas TDI is typically used for flexible foam applications. Blends of MDI and TDI are also used.

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